Projects
A. Research Projects
a. Emerging technologies and approaches to
minimize discharges into Lake Michigan, to be funded ($5M)
The objectives of
this multi-institutional project are to (1) screen emerging
technologies that could address wastewater treatment challenges
faced by BP and other entities along the Great Lakes; and (2) to
conduct a comparative analysis of related discharge issues that may
help policymakers better understand and address environmental
concerns. BP will use this information to investigate whether any
of the screened technologies could be applied at its Whiting
refinery, before renewal of the refinery's discharge permit in 2012,
to reduce environmental impacts while preserving the commercial
viability of its planned investment. BP is planning to
reconfigure the Whiting refinery to process more Canadian heavy
crude oil. There is a strong regional benefit to identify and
implement technologies that maintain water quality in Lake Michigan.
b. Sensor Technology (Don Gray,
George Nnanna, and Hal Pinnick)
Distribution Systems have been
recognized as the part of water supply systems that is most
vulnerable to deliberate contamination. In order to be truly
innovative, new monitoring systems need to be able to operate
unattended, online, in real time and be integrated into a
distributed sensor network that minimizes false positives and
negatives. The term "Sensor" is used to generally to describe
methods for detecting small molecules, cations (such as Na+,
Ca2+ and Hg2+), and anions (such as Cl-
and oxyanions such as AsO33- (AsIII) and AsO43-
(AsV)).
The PWI has embarked on two major
sensor projects: a) Multi-parameter sensors where a suit of
sensors (PH, turbidity, conductivity, dissolved oxygen) will be
instrumented in a water distribution piping network to detect
changes in physiochemical and thermal properties of water in the
presence of contaminants. In this effort, a lab-scale model of the
City of Hammond, IN, water piping network will be designed and
built, and sensors attached to pre-selected locations will monitor
the variations in contaminant concentration and properties. b)
Quartz
Crystal Microbalance (QCM) is a miniature scale which weighs the
presence of target ions or molecules. The crystal is excited
electronically and made to oscillate. The targets, the ions or
molecules, are attracted to the QCM that are deposited on the
surface of the crystal. The weight or mass of the target on the
receptor chemistry slows down the oscillations on the crystal
indicating the presence of the target. Presently, PWI is
collaborating with Quansor Corporation located at the Purdue
Research Park in this effort.
c. Mathematical Model of
Contaminant Transport (George Nnanna)
One of the fundamental problems in online water monitoring system is
determination of the optimum location of the sensor in order to
effectively detect the contaminant at high concentration. This study
is to develop a MATLAB code which will predict the concentration of
any contaminant which might be introduced into the drinking water
system. MATLAB is a powerful software package with many built in
functions useful in almost all engineering applications. Mass
balance equations are solved to get a governing equation which
contains concentration 'C' as a function of distances in 'x', 'y'
and 'z' directions and time 't'.
d. Predicting Northwest Indiana's
Water Quality (Ruijian Zhang)
Water quality prediction is becoming a major challenge in Northwest
Indiana and Lake Michigan region. Traditionally, mechanistic
simulation models are employed for water quality modeling and
prediction. However, the nature in Northwest Indiana and Lake
Michigan region is very complex, and even the most detailed
simulation model is extremely simple in comparison. At some point,
additional detail exceeds our ability to simulate and predict with
reasonable error levels. In those situations, two attractive
alternatives of water quality modeling and prediction may be to
express the complex behavior of the nature in Northwest Indiana and
Lake Michigan region. One of them applies Bayesian network to
predict the water quality probabilistically, as in statistical
mechanics. The other employs C5 as decision tree modeling tool to
make the water quality prediction. This study will investigate the
potential for probability network and decision tree models to
support water quality assessment and prediction in Northwest Indiana
and compare these two methods with conventional mechanistic models.
e. Validation of Inductively Coupled Plasma Spectroscopy (ICP),
(Anita Katti).
'The Inductively
Coupled Plasma Spectroscopy (ICP) measures and quantifies metals in
a solution in one step with a single introduction of sample. Its
design uses a sensor array to detect the signals of "all" metals
simultaneously. The ICP has been installed with access to a 220 V
line and an elephant trunk hood. Presently, a PWI faculty is testing
and validating the equipment. The ICP will be tested using
calibration standards and calibration standard mixture solutions
readily available from vendors and suppliers in order to master the
software as well as evaluate the accuracy and precision of the
instrument for selected elements. The ICP will be validated by
measuring the limit of detection and the limit of quantification for
the same selected metals.
f. Wastewater Reuse Assessment in
Northwest Indiana, William Rutherford and George Nnanna
The goal of this project is to
assess, through statistical analyses, the amount of wastewater
generated in the Northwest Indiana region that is being treated and
reused for other requirements on a county by county basis. This data
will then be used to determine methods to improve the quality of the
water. Included in this study are the amount of water that is
currently being consumed by agriculture, industry, and
residential/commercial groups and their corresponding sources.
g. Raltson
Street Lagoon Project, 2006, ($17,300.00), Gary Sanitary District
(GSD), Gary, IN, Awarded, George Nnanna, Hal Pinnick, Anita Kitta
The objective of
this project is to examine the reports submitted by CDM to GSD on
the current status of the PolyChlorinated Biphenyls (PCB) content of
the Ralston Street Lagoon. Based on assessment of the reports, the
Purdue Calumet Water Institute (PWI) will recommend an economically
feasible remediation plan for the lagoon.
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